86 Rn (222)

Radon

Noble gas Radon gas Radioactivity

[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p⁶ · 2 · 8 · 18 · 32 · 18 · 8

A radioactive noble gas that seeps out of the ground into basements. Radon is the second leading cause of lung cancer after smoking, and the first among non-smokers.

3D model

Bohr model: nucleus and electron shells from the real configuration. Valence electrons are highlighted.

Drag to rotate, scroll to zoom

Atomic properties

Atomic number
86
Atomic mass
222 а.е.м.
№33 / 118
Electron configuration
[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p⁶
Electrons per shell
2 · 8 · 18 · 32 · 18 · 8
Block
p-block
Group
Noble gases
Period
6
Electronegativity (Pauling)
2.2
№22 / 100
Electronegativity (Allen)
2.6
Atomic radius
120 pm
№82 / 103
Covalent radius
150 pm
№57 / 118
Van der Waals radius
220 pm
Ionisation energy 1
1 037 kJ/mol
№14 / 118
Electron affinity
kJ/mol
№101 / 108
Common oxidation states
0
Oxidation states
0, +2, +6

Physical properties

State at 25 °C
gas
Density
0.00973 g/cm³
№108 / 118
Melting point
202 K · -71.2 °C
№100 / 111
Boiling point
211.5 K · -61.7 °C
№98 / 107
Speed of sound
no data

Thermal properties

Heat of fusion
3.247 kJ/mol
№79 / 98
Heat of vaporisation
18.1 kJ/mol
№88 / 98
Specific heat capacity
0.094 J/(g·K)
№93 / 95
Thermal conductivity
0.00361 W/(m·K)
№96 / 96

Mechanical properties

Young's modulus
no data
Shear modulus
no data
Bulk modulus
no data
Poisson ratio
no data
Mohs hardness
no data
Brinell hardness
no data

Electrical and magnetic properties

Electrical resistivity
no data
Magnetic ordering
non-magnetic
Curie point
no data
Néel point
no data
Superconducting point
no data

Crystal structure

Crystal structure
face-centred cubic (fcc)
Lattice constants
no data

Abundance

In the crust
4·10⁻¹³ mg/kg
№88 / 88
In the ocean
mg/L
№78 / 78
In the universe
mg/kg
№83 / 83
In the human body
mg/kg
№40 / 40

Isotopes

Isotope Abundance Half-life Decay mode
219Rn 3.96 s α
220Rn 55.6 s α
222Rn 3.82 d α

Radon-222, half-life 3.8 days, is the daughter of radium-226 and the main source of public radiation dose. Radon-220, thoron, is shorter-lived and travels less far.

Discovery

Year of discovery
1900
№36 / 108
Discovered by
Friedrich Ernst Dorn
Where
Germany
Origin of the name
from radium, whose decay produces it

History

Friedrich Dorn noticed in 1900 that radium gives off a radioactive gas, which he called an emanation. Ramsay and Gray isolated it in 1910 and established it as the heaviest noble gas.

Where it occurs

Formed continuously by radium decay in rock. Air concentration depends on geology: granite and shale districts give noticeably more.

How it is produced

From radium sources. There is no practical production.

Role in living things

No biological role. Radon itself does not lodge in the lungs, but its solid decay products settle in the bronchi and irradiate the tissue with alpha particles.

Safety

The WHO attributes 3 to 14 % of all lung cancers to radon. The remedy is sub-floor ventilation and sealing foundations; many countries require a radon measurement when a house is sold.

Uses

  • Historically brachytherapy in sealed needles, now displaced by other isotopes
  • A geological tracer: radon flux maps faults and has been trialled for eruption forecasting
  • A tracer for studying air mass transport

Curiosities

  • Radon accounts for roughly half of the natural radiation dose an average person receives.
  • Radon is 7.5 times denser than air and pools in cellars and basements.
  • In the early twentieth century radon inhalations and radioactive water were sold as health treatments.
  • Radon is the one radioactive element most people encounter every single day.

Position in the table

Rn